Removal of malachite green dye from aqueous solution through inexpensive and easily available tuffite, bentonite and vitreous tuff minerals
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Tuffite (TUF), bentonite (BEN) and vitreous tuff (VT) accessible minerals were investigated as malachite green dye adsorbent materials. The morphology, textural and structural properties of the minerals were investigated by Scanning Electron Microscopy, Infrared Spectroscopy, X-Ray Diffraction, specific surface area (SBET), pH at zero charge, and chemical composition. The equilibrium times for BEN, TUF and VT minerals were 55 min, 80 min and 60 min, respectively. The best fit was achieved with a pseudo second-order model which may indicate that the adsorption process is dominated by chemisorption. The mechanism of adsorption was better described by film and intraparticle diffusion process. The adsorption capacities of dye onto VT, BEN and TUF were 71.22, 84.90 and 212.75 mg g-1. In a comparative study, the amount removal for acid green 25 dye were 130.30 mg g-1, 119.56 mg g-1 and 25.43 mg g-1, respectively. The removal of dyes occurred through a combination of mechanisms. The adsorption behavior in a fixed-bed system was better described by Bohart-Adams and Thomas model for Co=50 mg l-1 Co=100 mg l-1 respectively. TUF mineral could be employed as a very effective adsorbent for dyes removal002E.
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Blanco-Flores, A. (2016). Removal of malachite green dye from aqueous solution through inexpensive and easily available tuffite, bentonite and vitreous tuff minerals. Revista Latinoamericana De Recursos Naturales, 12(1), 1-17. Recuperado a partir de https://revista.itson.edu.mx/index.php/rlrn/article/view/244
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Acemioğlu, B. 2005. Batch kinetic study of sorption of methylene blue by perlite. Chemical Engineering Journal, 106: 73-81.
Almasi, A., Meghdad, P., Sohrab, A., Kiomars, S., Masoud, M., Yahya, J. 2016. Modeling and statistical analysis of malachite green dye removal from aqueous solutions by activated carbon powder prepared from Pine Bark (Modified by Sulfuric Acid)-Application of Response Surface Methodology. International Research Journal of Applied and Basic Sciences, 10: 5-12.
Arellano-Cárdenas, S., López-Cortez, S., Cornejo-Mazón, M., Mares-Gutiérrez, J.C. 2013. Study of malachite green adsorption by organically modified clay using a batch method. Applied Surface Science, 280: 74-78.
Batista, G. R., Coutin, D.P.C., González, C.D. Torres, Z.J.L. 2010. Valoración del potencial de las rocas y minerales industriales para el desarrollo municipal en la República de Cuba.
Blanco-Flores, A., Autie-Castro, G., Rodríguez-Montes, de Oca D., Paez, S.R., López-Cordero, R., Autie-Pérez, M. 2009. Características superficiales de un vidrio volcánico cubano y remoción de Cu2+ desde disoluciones acuosas. Revista Latinoamericana de Recursos Naturales, 5: 238-252.
Blanco-Flores, A., Colín-Cruz, A., Gutiérrez-Segura, E., Sánchez-Mendieta, V., Solís-Casados, D.A., Garrudo-Guirado, M.A., Batista-González, R. 2014. Efficient removal of crystal violet dye from aqueous solutions by vitreous tuff mineral. Environmental Technology, 35: 1508-1519.
Blanco-Varela, M.T., Martínez-Ramírez, S., Ereña, I., Gener, M. 2006. Pozzolanic reactivity of zeolitic rocks from two different Cuban deposits: Characterization of reaction products. Applied Clay Science, 32: 40-52.
Boonyawan, Y., Parncheewa, U., Buppa, P., Pawnprapa, K. 2010. Modification of calcite by hydration–dehydration method for heterogeneous biodiesel production process: The effects of water on properties and activity. Chemical Engineering Journal, 162: 135-141.
Bulut, E., Özacar, M., Şengil, I.A. 2008. Equilibrium and kinetic data and process design for adsorption of Congo Red onto bentonite. Journal of Hazardous Material, 154: 613-622.
Burcu, E.A., Özgϋr, A. 2012. The investigation of the effect of thermal treatment on bentonites from Turkey with Fourier transform infrared and solid state nuclear magnetic resonance spectroscopic methods. Spectrochimica Acta Part A, 94: 331-333.
Chinenye, A., Pius, C., Okechukwu, D., Ikenna, C. 2016. Adsorptive Treatment of Textile Wastewater Using Activated Carbon Produced from Mucuna pruriens Seed Shells. World Journal of Engineering and Technology, 4: 21-37.
El-Sayed, G.O. 2011. Removal of methylene blue and crystal violet from aqueous solutions by palm kernel fiber. Desalination, 272: 225-232.
Erdal, E. 2009. Removal of lead ions by Unye (Turkey) bentonite in iron and magnesium oxide-coated forms. Journal of Hazardous Material, 165: 63-70.
Faria, P.C.C., Órfão, J.J.M., Pereira, M.F.R. 2004. Adsorption of anionic and cationic dyes on activated carbons with different surface chemistries. Water Research, 38: 2043-2052.
Ghaedi, M., Ansari, A., Habibi, M.H., Asghari, A.R. 2014. Removal of malachite green from aqueous solution by zinc oxide nanoparticle loaded on activated carbon: Kinetics and isotherm study. Journal of Industrial Engineering Chemistry, 20: 17-28.
Gopinathan, R., Kanhere, J., Banerjee, J. 2015. Effect of malachite green toxicity on non-target soil organisms. Chemosphere, 120: 637-64.
Gupta, V.K.2009. Application of low-cost adsorbents for dye removal-A review. Journal of Environmental Management, 90: 2313-2342.
Gutiérrez-Segura, E., Solache-Ríos, M., Colín-Cruz, A., Fall, C. 2012. Adsorption of cadmium by Na and Fe modified zeolitic tuffs and carbonaceous material from pyrolyzed sewage sludge. Journal of Environmental Management, 97: 6-13.
Han, K., Sung-Oong, K., Sungyoul, P., Ho, S.P. 2015. Adsorption isotherms and kinetics of cationic and anionic dyes on three-dimensional reduced graphene oxide macrostructure. Journal of Industrial and Engineering Chemistry, 21: 191-1196.
Himanshu, P., Vashi, R.T. 2012. Fixed bed column adsorption of acid yellow 17 dye onto Tamarind seed power. Canadian Journal Chemical Engineering, 90: 180-185.
Kabra, S., Katara, S., Rani, A. 2013. Characterization and study of Turkish perlite. International Journal of Innovative Research in Science Engineering and Technology, 2: 4319-4325.
Kosmulski, M. 2009. pH-dependent surface charging and points of zero charge. IV. Update and new approach. Journal of Colloid and Interface Science, 337: 439-448.
Kruk, M., Jaroniec, M. 2001. Gas adsorption characterization of ordered organic-inorganic nanocomposite materials. Chemistry of Material, 13: 3169-3183.
Kumar, K.A., Gupta, N., Chattopadhyaya, M.C. 2011. Removal of cationic methylene blue and malachite green dyes from aqueous solution by waste materials of Daucus carota. Journal of Saudi Chemical Society, 18: 200-207.
Kurniawan, A., Hogiartha, S., Indraswati, N., Ismadji, S. 2012. Removal of basic dyes in binary system by adsorption using Rarasaponin-bentonite: Revisited of extended Langmuir model. Chemical Engineering Journal, 189: 264- 274.
Lunhong, A., Chunying, Z., Fang, L., Yao, W., Ming, L., Lanying, M., Jing, J. 2011. Removal of methylene blue from aqueous solution with magnetite loaded multi-wall carbon nanotube: Kinetic, isotherm and mechanism analysis. Journal of Hazardous Materials, 198: 282- 290.
McBride, J.H., Spencer, W.G., Faust, L.D., Nelson, T.S. 2012. A structural study of thermal tufas using ground-penetrating radar. Journal of Applied Geophysics, 81: 38-47.
Önal, Y., Akmil-Başar, C., Didem, E., Sarıcı-Özdemir, Ç., Depci, T. 2006. Adsorption kinetics of malachite green onto activated carbon prepared from Tunçbilek lignite. Journal of Hazardous Materials, B128: 150-157.
Orozco, G., Rizo, R. 1998. Depósitos de zeolitas naturales de Cuba. Acta geológica hispánica, 33: 335-349.
Qian, L., Qin-Yan, Y., Hong-Jian, S., Yuan, S., Bao-Yu, G. 2010. A comparative study on the properties, mechanisms and process designs for the adsorption of non-ionic or anionic dyes onto cationic-polymer/bentonite. Journal of Environmental Management, 91: 1601-1611.
Qiangshan, J., Linxia, F., Hongyan, L., Peng, L. 2011. Preparation of surface-vitrified micron sphere using perlite from Xinyang, China. Applied Clay Science, 53: 745-748.
Ramya, Vinayagam, M., Murugan, D., Lajapathirai, C., Saravanan, P., Sivasamy, A. 2016. Adsorption of Malachite Green onto Chemically Activated Carbon Prepared from Waste Biomass. International Journal of Innovative Research in Science, Engineering and Technology, 5: 115-123.
Roulia, M., Vassiliadis, A.A. 2008. Sorption characterization of a cationic dye retained by clays and perlite. Microporous Mesoporous Materials, 116: 732-740.
Sarı, A., Karaipekli, A., Alkan, C. 2009. Preparation, characterization and thermal properties of lauric acid/expanded perlite as novel form-stable composite phase change material. Chemical Engineering Journal, 155: 899-904.
Silber, A., Bar-Yosef, B., Levkovitch, I., Soryano, S. 2010. pH-Dependent surface properties of perlite: Effects of plant growth. Geoderma, 158: 275-281.
Thompson, P.S., Day, J.S., Parker, E.J., Evans, A., Chiu, T.C. 2012. Fine-grained amorphous calcium silicate CaSiO3 from vacuum dried sol-gel-Production, characterization and thermal behavior. Journal Non-Crystalline Solids, 358: 885-892.
Toor, M., Bo, J. 2012. Adsorption characteristics, isotherm, kinetics, and diffusion of modified natural bentonite for removing diazo dye. Chemical Engineering Journal, 187: 79-88.
Tsai, W.T., Chen, H.P., Lai, C.W., Hsien, K.J., Lee, M.S., Yang, J.M. 2003. Preparation of adsorbents from sugarcane manufacturing by-product filter-mud by thermal activation. Journal of Analytical and Applied Pyrolysis, 70: 399-411.
Venkat, S., Vijay, B.P.V. 2011. Studies on the adsorption of Brilliant Green dye from aqueous solution onto low-cost NaOH treated saw dust. Desalination, 273: 321-329.
Vieira, M.G.A., Almeida, N.A.F., Gimenes, M.L., da Silva, M.G.C. 2010. Removal of nickel on Bofe bentonite calcined clay in porous bed. Journal of Hazardous Materials, 17: 109-118.
Xianming, M., Liping, L., Lin, C., Caiyun, S., Kwi, W., Shibao, Y., Jianguo, Z. 2012. Adsorption of heavy metal ions using hierarchical isotherm and kinetics studies. Journal of Hazardous Materials, 209: 467-477.
Young-Chul, L., Jin-Young, K., Hyun-Jae, S. 2013. Removal of malachite green (MG) from aqueous solutions by adsorption, precipitation, and alkaline fading using talc. Separation Science and Technology, 48: 1093-1101.
Almasi, A., Meghdad, P., Sohrab, A., Kiomars, S., Masoud, M., Yahya, J. 2016. Modeling and statistical analysis of malachite green dye removal from aqueous solutions by activated carbon powder prepared from Pine Bark (Modified by Sulfuric Acid)-Application of Response Surface Methodology. International Research Journal of Applied and Basic Sciences, 10: 5-12.
Arellano-Cárdenas, S., López-Cortez, S., Cornejo-Mazón, M., Mares-Gutiérrez, J.C. 2013. Study of malachite green adsorption by organically modified clay using a batch method. Applied Surface Science, 280: 74-78.
Batista, G. R., Coutin, D.P.C., González, C.D. Torres, Z.J.L. 2010. Valoración del potencial de las rocas y minerales industriales para el desarrollo municipal en la República de Cuba.
Blanco-Flores, A., Autie-Castro, G., Rodríguez-Montes, de Oca D., Paez, S.R., López-Cordero, R., Autie-Pérez, M. 2009. Características superficiales de un vidrio volcánico cubano y remoción de Cu2+ desde disoluciones acuosas. Revista Latinoamericana de Recursos Naturales, 5: 238-252.
Blanco-Flores, A., Colín-Cruz, A., Gutiérrez-Segura, E., Sánchez-Mendieta, V., Solís-Casados, D.A., Garrudo-Guirado, M.A., Batista-González, R. 2014. Efficient removal of crystal violet dye from aqueous solutions by vitreous tuff mineral. Environmental Technology, 35: 1508-1519.
Blanco-Varela, M.T., Martínez-Ramírez, S., Ereña, I., Gener, M. 2006. Pozzolanic reactivity of zeolitic rocks from two different Cuban deposits: Characterization of reaction products. Applied Clay Science, 32: 40-52.
Boonyawan, Y., Parncheewa, U., Buppa, P., Pawnprapa, K. 2010. Modification of calcite by hydration–dehydration method for heterogeneous biodiesel production process: The effects of water on properties and activity. Chemical Engineering Journal, 162: 135-141.
Bulut, E., Özacar, M., Şengil, I.A. 2008. Equilibrium and kinetic data and process design for adsorption of Congo Red onto bentonite. Journal of Hazardous Material, 154: 613-622.
Burcu, E.A., Özgϋr, A. 2012. The investigation of the effect of thermal treatment on bentonites from Turkey with Fourier transform infrared and solid state nuclear magnetic resonance spectroscopic methods. Spectrochimica Acta Part A, 94: 331-333.
Chinenye, A., Pius, C., Okechukwu, D., Ikenna, C. 2016. Adsorptive Treatment of Textile Wastewater Using Activated Carbon Produced from Mucuna pruriens Seed Shells. World Journal of Engineering and Technology, 4: 21-37.
El-Sayed, G.O. 2011. Removal of methylene blue and crystal violet from aqueous solutions by palm kernel fiber. Desalination, 272: 225-232.
Erdal, E. 2009. Removal of lead ions by Unye (Turkey) bentonite in iron and magnesium oxide-coated forms. Journal of Hazardous Material, 165: 63-70.
Faria, P.C.C., Órfão, J.J.M., Pereira, M.F.R. 2004. Adsorption of anionic and cationic dyes on activated carbons with different surface chemistries. Water Research, 38: 2043-2052.
Ghaedi, M., Ansari, A., Habibi, M.H., Asghari, A.R. 2014. Removal of malachite green from aqueous solution by zinc oxide nanoparticle loaded on activated carbon: Kinetics and isotherm study. Journal of Industrial Engineering Chemistry, 20: 17-28.
Gopinathan, R., Kanhere, J., Banerjee, J. 2015. Effect of malachite green toxicity on non-target soil organisms. Chemosphere, 120: 637-64.
Gupta, V.K.2009. Application of low-cost adsorbents for dye removal-A review. Journal of Environmental Management, 90: 2313-2342.
Gutiérrez-Segura, E., Solache-Ríos, M., Colín-Cruz, A., Fall, C. 2012. Adsorption of cadmium by Na and Fe modified zeolitic tuffs and carbonaceous material from pyrolyzed sewage sludge. Journal of Environmental Management, 97: 6-13.
Han, K., Sung-Oong, K., Sungyoul, P., Ho, S.P. 2015. Adsorption isotherms and kinetics of cationic and anionic dyes on three-dimensional reduced graphene oxide macrostructure. Journal of Industrial and Engineering Chemistry, 21: 191-1196.
Himanshu, P., Vashi, R.T. 2012. Fixed bed column adsorption of acid yellow 17 dye onto Tamarind seed power. Canadian Journal Chemical Engineering, 90: 180-185.
Kabra, S., Katara, S., Rani, A. 2013. Characterization and study of Turkish perlite. International Journal of Innovative Research in Science Engineering and Technology, 2: 4319-4325.
Kosmulski, M. 2009. pH-dependent surface charging and points of zero charge. IV. Update and new approach. Journal of Colloid and Interface Science, 337: 439-448.
Kruk, M., Jaroniec, M. 2001. Gas adsorption characterization of ordered organic-inorganic nanocomposite materials. Chemistry of Material, 13: 3169-3183.
Kumar, K.A., Gupta, N., Chattopadhyaya, M.C. 2011. Removal of cationic methylene blue and malachite green dyes from aqueous solution by waste materials of Daucus carota. Journal of Saudi Chemical Society, 18: 200-207.
Kurniawan, A., Hogiartha, S., Indraswati, N., Ismadji, S. 2012. Removal of basic dyes in binary system by adsorption using Rarasaponin-bentonite: Revisited of extended Langmuir model. Chemical Engineering Journal, 189: 264- 274.
Lunhong, A., Chunying, Z., Fang, L., Yao, W., Ming, L., Lanying, M., Jing, J. 2011. Removal of methylene blue from aqueous solution with magnetite loaded multi-wall carbon nanotube: Kinetic, isotherm and mechanism analysis. Journal of Hazardous Materials, 198: 282- 290.
McBride, J.H., Spencer, W.G., Faust, L.D., Nelson, T.S. 2012. A structural study of thermal tufas using ground-penetrating radar. Journal of Applied Geophysics, 81: 38-47.
Önal, Y., Akmil-Başar, C., Didem, E., Sarıcı-Özdemir, Ç., Depci, T. 2006. Adsorption kinetics of malachite green onto activated carbon prepared from Tunçbilek lignite. Journal of Hazardous Materials, B128: 150-157.
Orozco, G., Rizo, R. 1998. Depósitos de zeolitas naturales de Cuba. Acta geológica hispánica, 33: 335-349.
Qian, L., Qin-Yan, Y., Hong-Jian, S., Yuan, S., Bao-Yu, G. 2010. A comparative study on the properties, mechanisms and process designs for the adsorption of non-ionic or anionic dyes onto cationic-polymer/bentonite. Journal of Environmental Management, 91: 1601-1611.
Qiangshan, J., Linxia, F., Hongyan, L., Peng, L. 2011. Preparation of surface-vitrified micron sphere using perlite from Xinyang, China. Applied Clay Science, 53: 745-748.
Ramya, Vinayagam, M., Murugan, D., Lajapathirai, C., Saravanan, P., Sivasamy, A. 2016. Adsorption of Malachite Green onto Chemically Activated Carbon Prepared from Waste Biomass. International Journal of Innovative Research in Science, Engineering and Technology, 5: 115-123.
Roulia, M., Vassiliadis, A.A. 2008. Sorption characterization of a cationic dye retained by clays and perlite. Microporous Mesoporous Materials, 116: 732-740.
Sarı, A., Karaipekli, A., Alkan, C. 2009. Preparation, characterization and thermal properties of lauric acid/expanded perlite as novel form-stable composite phase change material. Chemical Engineering Journal, 155: 899-904.
Silber, A., Bar-Yosef, B., Levkovitch, I., Soryano, S. 2010. pH-Dependent surface properties of perlite: Effects of plant growth. Geoderma, 158: 275-281.
Thompson, P.S., Day, J.S., Parker, E.J., Evans, A., Chiu, T.C. 2012. Fine-grained amorphous calcium silicate CaSiO3 from vacuum dried sol-gel-Production, characterization and thermal behavior. Journal Non-Crystalline Solids, 358: 885-892.
Toor, M., Bo, J. 2012. Adsorption characteristics, isotherm, kinetics, and diffusion of modified natural bentonite for removing diazo dye. Chemical Engineering Journal, 187: 79-88.
Tsai, W.T., Chen, H.P., Lai, C.W., Hsien, K.J., Lee, M.S., Yang, J.M. 2003. Preparation of adsorbents from sugarcane manufacturing by-product filter-mud by thermal activation. Journal of Analytical and Applied Pyrolysis, 70: 399-411.
Venkat, S., Vijay, B.P.V. 2011. Studies on the adsorption of Brilliant Green dye from aqueous solution onto low-cost NaOH treated saw dust. Desalination, 273: 321-329.
Vieira, M.G.A., Almeida, N.A.F., Gimenes, M.L., da Silva, M.G.C. 2010. Removal of nickel on Bofe bentonite calcined clay in porous bed. Journal of Hazardous Materials, 17: 109-118.
Xianming, M., Liping, L., Lin, C., Caiyun, S., Kwi, W., Shibao, Y., Jianguo, Z. 2012. Adsorption of heavy metal ions using hierarchical isotherm and kinetics studies. Journal of Hazardous Materials, 209: 467-477.
Young-Chul, L., Jin-Young, K., Hyun-Jae, S. 2013. Removal of malachite green (MG) from aqueous solutions by adsorption, precipitation, and alkaline fading using talc. Separation Science and Technology, 48: 1093-1101.